No, not natively. The Xbox Series X only recognizes controllers that pass Microsoft's Xbox authentication handshake, and a PS3 DualShock 3 doesn't, whether plugged in via USB or paired over Bluetooth. The console will simply ignore it (Easy Info Hub, SlashGear).
The only reliable workaround is a third-party converter, such as the Brook Wingman XB 3 (or the older Wingman XB). It plugs into the console and translates the DualShock 3's input into a valid Xbox signal, with support for button remapping and firmware updates. It adds a bit of cost and a small adapter in the chain, but it's the standard solution people use for this (ADZ Gaming, Brook Gaming).
So: fine on a PS3 or PC (with drivers/tools like Steam), but on an Xbox Series X you'd need an adapter in between.
Nov 5, 5:00pm
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